91120-88-6Relevant articles and documents
Fluorination of Adamantane Derivatives with Oxygen Difluoride
Bolte, Gerd,Haas, Alois
, p. 1982 - 1986 (2007/10/02)
Fluorination of adamantane and adamantane derivatives 1 with OF2 in the absence of an HF-trap gives fluoroadamantanes 2 and adamantanols 3 in varying amounts.Increasing yields of 2 are obtained in the presence of Na2CO3 as an HF-trap.In addition, the fluorooxahomoadamantanes 4b and e are formed in this reaction.The fluorination of adamantanone (5) with OF2 leads to analogous products.