911207-83-5

Upstream product

• 925-90-6 ethylmagnesium bromide 
• 167282-09-9 (-)-((4R,5R)-5-benzoyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-phenyl-methanone 
• 370103-83-6 (+)-(4R,5R)-1-(2,2-dimethyl-5-propionyl-[1,3]dioxolan-4-yl)-propan-1-one 
• 177283-77-1 (4R,5R)-N,N'-dimethoxy-N,N',2,2-tetramethyl-1,3-dioxolane-4,5-dicarboxamide 

Downstream Products

• 912646-30-1 (3S,4R,5R,6S)-3,6-dimethoxy-3,6-diphenyloctane-4,5-diol 
• 912646-28-7 (4R,5R)-4,5-bis((S)-1-methoxy-1-phenylpropyl)-2,2-dimethyl-1,3-dioxolane 

Relevant academic research and scientific papers

Nucleophilic addition reactions of 1,4-diketones derived from tartaric acid: Synthesis of TADDOL analogues

A systematic investigation of the reduction and Grignard reagents addition to 1,4-diketones derived from tartaric acid was carried out. It was found that the reduction proceeded with high selectivity using K-Selectride as the reducing agent; while Grignar

Asymmetric synthesis of both enantiomers of α-methyl-α-methoxyphenylacetic acid from l-(+)-tartaric acid: formal enantioselective synthesis of insect pheromone (-)-frontalin

Both antipodes of α-methyl-α-methoxyarylacetic acid derivatives were prepared from a common chiralpool precursor l-(+)-tartaric acid. The key step involves the addition of Grignard reagents to 1,4-diketones derived from tartaric acid. The utility of this