911371-53-4

Upstream product

• 1311161-38-2 C₉H₁₄O₄ 
• 1311161-37-1 (4R,5R)-1-(2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-2-(tert-butyldiphenylsilyloxy)ethan-1-one 
• 34626-95-4 1,2:3,4-di-O-isopropylidene-β-D-psicofuranose 
• 38084-06-9 6-deoxy-6-iodo-1,2:3,4-di-O-isopropylidene-D-psicofuranose 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 911371-54-5 (2R,3S,4R)-1-O-(tert-butyl(diphenyl)silyl)-3,4-O-isopropylidene-15-methyl-5-hexadecene-1,2,3,4-tetrol 
• 1311161-43-9 2-((R)-2-(tert-butyldiphenylsilyloxy)-2-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)isoindoline-1,3-dione 
• 148695-00-5 (2S,3S,4R)-N-[(R)-2-acetoxytetracosanoyl]-2-amino-3,4-di-O-benzoyl-16-methylheptadecane-1,3,4-triol 
• 911371-66-9 (2S,3S,4R)-N-[(R)-2-acetoxytetracosanoyl]-2-amino-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-16-methylheptadecane-1,3,4-triol 
• 911371-65-8 (2S,3S,4R)-N-[(R)-2-acetoxypentacosanoyl]-2-amino-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-15-methylhexadecane-1,3,4-triol 
• 911371-72-7 (2S,3S,4R)-N-[(R)-2-acetoxypentacosanoyl]-2-amino-3,4-di-O-benzoyl-15-methylhexadecane-1,3,4-triol 
• 911371-61-4 (2S,3S,4R)-2-azido-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-16-methylheptadecane-1,3,4-triol 
• 911371-60-3 (2S,3S,4R)-2-azido-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-15-methylhexadecane-1,3,4-triol 
• 911371-63-6 (2S,3S,4R)-2-amino-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-16-methylheptadecane-1,3,4-triol 
• 911371-62-5 (2S,3S,4R)-2-amino-3,4-di-O-benzoyl-1-O-(tert-butyl(diphenyl)silyl)-15-methylhexadecane-1,3,4-triol 
• 911371-59-0 (2S,3S,4R)-2-azido-1-O-(tert-butyl(diphenyl)silyl)-3,4-O-isopropylidene-16-methylheptadecane-1,3,4-triol 
• 911371-58-9 (2S,3S,4R)-2-azido-1-O-(tert-butyl(diphenyl)silyl)-3,4-O-isopropylidene-15-methylhexadecane-1,3,4-triol 
• 911371-57-8 (2R,3S,4R)-1-O-(tert-butyl(diphenyl)silyl)-3,4-O-isopropylidene-16-methylheptadecane-1,2,3,4-tetrol 
• 911371-56-7 (2R,3S,4R)-1-O-(tert-butyl(diphenyl)silyl)-3,4-O-isopropylidene-15-methylhexadecane-1,2,3,4-tetrol 

Relevant academic research and scientific papers

An unexpected migration of O-silyl group under Mitsunobu reaction conditions

A 1,4 O→O silyl migration followed by nucleophilic substitution with phthalimide was observed under Mitsunobu reaction conditions. This one step secondary alcohol protection and primary alcohol substitution with N-nucleophiles was extended to a variety of

Total synthesis of agelagalastatin

The total synthesis of-agelagalastatin, an antineoplastic glycosphingolipid, has been achieved. The synthesis involved an α-selective glycosylation of the ceramide moiety with the trisaccharide fluoride. The trisaccharide component was constructed employi