911464-87-4

Upstream product

• 13677-54-8 1,3-bis(4-chlorophenyl)prop-2-en-1-ol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 911464-83-0 [(E)-(R)-2,4-Bis-(4-chloro-phenyl)-but-3-enyl]-carbamic acid tert-butyl ester 
• 911464-93-2 Carbonic acid (E)-1,3-bis-(4-chloro-phenyl)-allyl ester ethyl ester 
• 911465-10-6 C₁₆H₁₃Cl₂NO₂ 

Downstream Products

• 144564-11-4 (R)-tert-butyl 4-(4-chlorophenyl)-2-oxopyrrolidine-1-carboxylate 

Relevant academic research and scientific papers

Pd-catalyzed asymmetric allylic alkylation with nitromethane using a chiral diaminophosphine oxide: (S,RP)-Ph-DIAPHOX. Enantioselective synthesis of (R)-preclamol and (R)-baclofen

A Pd-catalyzed asymmetric allylic alkylation with nitromethane using an aspartic acid-derived P-chirogenic diaminophosphine oxide [(S,RP)-Ph-DIAPHOX] is described. This method was successfully applied to enantioselective synthesis of (R)-precla