91154-14-2Relevant academic research and scientific papers
THE ALKYLATION OF AN α,α'-DIANINON IN A β-KETOSULPHONE LEADING TO THE PREPARATION OF AXIAL 2-SUBSTITUED THIANE-1,1-DIOXIDES
Grossert, J. Stuart,Hoyle, Jeffrey,Hooper, Donald L.
, p. 1090 - 1140 (2007/10/02)
The 1,3-dianion formed across the sulphone of a β-ketosulphone may be selectively dialkylated in a controlled way with an α,ο-difunctional electrophyle to give a 2-ketothiane-1,1-dioxide.Polar groups in the 2-position of thiane-1,1-dioxides preferentially
