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Trischlorotris(ethyl N-phenyldithiocarbamate)rhodium(III) is a coordination complex with the chemical formula [Rh(C6H5NS2C2H5)3Cl3]. It is a dark red-brown crystalline solid, known for its catalytic properties in various chemical reactions, particularly in the hydrogenation of alkenes and alkynes. trischlorotris(ethyl N-phenyldithiocarbamate)rhodium(III) consists of a rhodium(III) center coordinated to three ethyl N-phenyldithiocarbamate ligands and three chloride ions. The ethyl N-phenyldithiocarbamate ligands are bidentate, forming strong bonds with the rhodium center through sulfur and nitrogen atoms. Trischlorotris(ethyl N-phenyldithiocarbamate)rhodium(III) is widely used in the pharmaceutical and chemical industries as a homogeneous catalyst, facilitating selective transformations and improving reaction efficiency.

91155-06-5

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91155-06-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 91155-06-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,1,1,5 and 5 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 91155-06:
(7*9)+(6*1)+(5*1)+(4*5)+(3*5)+(2*0)+(1*6)=115
115 % 10 = 5
So 91155-06-5 is a valid CAS Registry Number.

91155-06-5Downstream Products

91155-06-5Relevant academic research and scientific papers

Complexing Behaviour of Ethyl N-Phenyldithiocarbamate: Structural Studies of Complexes of Fe(II), Ru(II), Co(II), Rh(III), Rh(I), Ni(II), Pd(0), Pt(0), Pt(II), Ag(I), Zn(II), Cd(II) and Hg(II)

Arulsamy, K. S.,Ashok, R. F. N.,Agarwala, U. C.

, p. 127 - 132 (2007/10/02)

Complexes of Fe(II), Ru(II), Co(II), Rh(III), Rh(I), Ni(II) and Pd(0), Pt(0), Pt(II), Ag(I), Zn(II), Cd(II) and Hg(II) with ethyl N-phenyldithiocarbamate have been synthesised.The complexes are characterised by elemental analyses, magnetic moment, conductivity and spectral (IR, UV-visible) data.It is proposed that bonding of metal ions with the ligand takes place through thiocarbonyl sulphur and the ligand acts as monodentate.

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