91173-72-7Relevant academic research and scientific papers
REACTION OF 5-BROMO-5-NITRO-1,3-DIOXANE WITH THE LITHIUM SALTS OF 5-NITRO-1,3-DIOXANE AND 2-NITROPROPANE
Zorin, V.V.,Kukovitskii, D.M.,Zlot-skii, S.S.,Todres, Z.V.,Rakhmankulov, D.L.
, p. 785 - 789 (2007/10/02)
5-Nitro-5-(5-nitro-1,3-dioxa-5-cyclohexyl)-1,3-dioxane and 5-(1,3-dioxa-5-cyclohexylidene)-1,3-dioxane are formed and lithium bromide and nitrite are released in the reaction of 5-bromo-5-nitro-1,3-dioxane with the lithium salt of 5-nitro-1,3-dioxane in DMSO at 20 deg C.The selectivity of the formation of the reaction products depends on the ratio of the reagents. 5-Nitro-5-(2-nitro-1-methylethyl)-1,3-dioxane, 5-nitro-5-(5-nitro-1,3-dioxa-5-cyclohexyl)-1,3-dioxane, and 2,3-dimethyl-2,3-dinitrobutane are formed in the reaction of 5-bromo-5-nitro-1,3-dioxane with the lithium salt of 2-nitropropane.The reaction is accelerated by UV radiation and is retarded in the presence of the inhibitors of radical reactions.
