91176-34-0Relevant academic research and scientific papers
Highly Stereocontrolled Construction of Tricyclo1,6>dodecanes by Intramolecular Double Michael Reaction
Ihara, Masataka,Toyota, Masahiro,Abe, Mariko,Ishida, Yohhei,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1543 - 1550 (2007/10/02)
o-Anisaldehyde has been converted, via a sigmatropic reaction and a Birch reduction, into the cyclohexenone (10) bearing an α,β-unsaturated group.Treatment of the latter with lithium hexamethyldisilazide induced an intramolecular double Michael react
STEREOCONTROLLED CONSTRUCTION OF A SPIRO FUSED BICYCLOOCTANE RING SYSTEM BY THE INTRAMOLECULAR DOUBLE MICHAEL REACTION
Ihara, Masataka,Toyota, Masahiro,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 2167 - 2170 (2007/10/02)
The lithium enolate from the cyclohexenone (8) possessing the α,β-unsaturated ester moiety caused an intramolecular double Michael reaction to produce stereoselectively the spiro fused bicyclo-octane (10).
