911800-21-0

Basic information

• Product Name: 4-morpholino-2-phenyl-1-oxa-spiro<2,5>-4-octene-2-carbonitrile
• CAS NO: 911800-21-0
• Molecular Weight: 296.369
• Mol File: 911800-21-0.mol

Chemical Properties

• CAS DataBase Reference: 4-morpholino-2-phenyl-1-oxa-spiro<2,5>-4-octene-2-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 4-morpholino-2-phenyl-1-oxa-spiro<2,5>-4-octene-2-carbonitrile(911800-21-0)
• EPA Substance Registry System: 4-morpholino-2-phenyl-1-oxa-spiro<2,5>-4-octene-2-carbonitrile(911800-21-0)

Safety Data

• Hazardous Substances Data: 911800-21-0(Hazardous Substances Data)

Upstream product

• 13435-20-6 tetraethylammoniumcyanide 
• 133147-62-3 1α,5α,6β-1-benzoyl-6-morpholino-bicyclo<3.1.0>hexane-6-carbonitrile 

Relevant articles and documents

FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS - V. SYNTHESIS AND REACTIONS OF AMINOCYCLOPROPYLKETONES

Conjugated acylated chloroenamines 5A,C were available by chlorination of mixtures of acylated enamines 8A,C/9A,C by NCS at 0 deg C.Nonconjugated chloroenamines 10Aa and 10Ba could be obtained by NCS-chlorination of the conjugated acylenamines 9A,B at low temperature.Reaction of 5Aa-5Ac, 5Ae, 5Af with cyanide produced morpholinocyclopropylketones 11A.In two cases aminofurans 12Ad and 12Ca resulted as products of this reaction.More generally amino-aryl-furans 12 were formed by thermolysis of the aryl-cyclopropylketones 11.Amino-alkyl-furans as 12Ae and 12Af only could be trapped by a Diels-Alder reaction leading to 16Ae and 16Af.Epoxyenamines 29A,B unexpectedly were produced from the interaction of cyanide with the chloroenamines 10Aa and 10Ba.