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CAS

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91200-45-2

Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1S)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 91200-45-2 Structure

  • Basic information

    1. Product Name: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1S)-
    2. Synonyms:
    3. CAS NO:91200-45-2
    4. Molecular Formula: C16H20
    5. Molecular Weight: 212.335
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 91200-45-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1S)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1S)-(91200-45-2)
    11. EPA Substance Registry System: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1S)-(91200-45-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 91200-45-2(Hazardous Substances Data)

91200-45-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 91200-45-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,1,2,0 and 0 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 91200-45:
(7*9)+(6*1)+(5*2)+(4*0)+(3*0)+(2*4)+(1*5)=92
92 % 10 = 2
So 91200-45-2 is a valid CAS Registry Number.

91200-45-2Downstream Products

91200-45-2Relevant articles and documents

Modifizierte Isopinocampheyldibromoborane; selektive Katalysatoren fuer asymmetrische Diels-Alder-Rekationen

Bir, Gerhard,Kaufmann, Dieter

, p. 1 - 6 (2007/10/02)

The synthesis of C-10 phenyl- and t-butyl modified isopinocampheyldibromoboranes is described.Their ability to act as chiral catalysts in asymmetric Diels-Adler reactions has been investigated as exemplified by the reaction of cyclopentadiene with methylacrylate.

THE REGIOSELECTIVITY OF RHODIUM AND PALLADIUM-CATALYSED CYCLISATIONS OF 2-BROMO-1,6- AND 1,7-DIENES

Grigg, Ronald,Stevenson, Paul,Worakun, Tanachat

, p. 2033 - 2048 (2007/10/02)

2-bromo-1,6-dienes are catalytically cyclised to a mixture of the corresponding 3,4-bis(methylene)cyclopentane and 5-methylenecyclohex-3-ene.Wilkinson's catalyst shows good selectivity for the 5-membered ring product whilst palladium catalysts, in general, show little selectivity.Addition of tetraethylammonium salts, especially the chloride, allow the palladium catalysed reactions to be carried out at 30 deg C in good yield and with high selectivity for the 5-membered ring. 2-Bromo-1,7-dienes are cyclised regiospecifically to 6-membered rings by the same catalysts although some double bond isomerisation also occurs.The mechanism of the catalytic cyclisations is discussed.The 3,4-bis(methylene) cyclopentanes undergo facile Diels-Alder reactions.

ALKYLATION DE TERPENES EN DEUX ETAPES PAR ENE-REACTION

Deleris, G.,Dunogues, J.,Gadras, A.

, p. 2135 - 2138 (2007/10/02)

A simple, two-step homologation of terpenes is reported that requires ene-reaction with PhSO2NSO and subsequent of the intermediate adducts with CuI catalyzed Grignard

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