91202-37-8Relevant academic research and scientific papers
Palladium-Catalyzed Mizoroki-Heck Reaction of Nitroarenes and Styrene Derivatives
Okita, Toshimasa,Asahara, Kitty K.,Muto, Kei,Yamaguchi, Junichiro
supporting information, p. 3205 - 3208 (2020/04/10)
We have developed a Mizoroki-Heck reaction of nitroarenes with alkenes under palladium catalysis. The use of a Pd/BrettPhos catalyst promoted the alkenylation, whereas other catalysts led to a decrease in the product yield. In addition to nitroarenes, nitroheteroarenes were also applicable to the present reaction. The combination of a nucleophilic aromatic substitution (SNAr) with the denitrative alkenylation produced a multifunctionalized arene in a one-pot operation.
A ligand free and room temperature protocol for Pd-catalyzed kumada-corriu couplings of unactivated alkenyl phosphates
Gauthier, Delphine,Beckendorf, Stephan,Gogsig, Thomas M.,Lindhardt, Anders T.,Skrydstrup, Troels
supporting information; experimental part, p. 3536 - 3539 (2009/09/30)
Kumada - Corriu cross-couplings of nonactivated cyclic and acyclic vinyl phosphates with aryl magnesium reagents afforded a series of 1,1-disubtituted alkenes in good yields for most cases when the reactions were performed at room temperature with the sim
Reactions of Azo and Azoxy Sulphones with Transition Metal Complexes. Part 7. Arylation of Olefins with Arylazoxy Aryl Sulphones Catalysed by a Palladium(0) Phosphine Complex
Kamigata, Nobumasa,Fukushima, Takamasa,Satoh, Akira,Kameyama, Masayuki
, p. 549 - 553 (2007/10/02)
The arylation of acyclic and cyclic olefins by arylazoxy aryl sulphones has been investigated in the presence of a palladium(0) catalyst in benzene.Both of the aryl groups of the arylazoxy aryl sulphones are found to participate in the arylation.Two equivalents of aryl-substituted olefins were obtained when the reactions were carried out at 80 deg C, whereas one equivalent of olefin was arylated at 120 deg C.A plausible catalytic cycle involving a diarylpalladium(II) species is proposed.
Photochemistry and Photophysics of Surfactant trans-Stilbenes in Supported Multilayers and Films at the Air-Water Interface
Mooney, William F.,Brown, Patti E.,Russell, John C.,Costa, Silvia B.,Pedersen, Lee G.,Whitten, David G.
, p. 5659 - 5667 (2007/10/02)
The synthesis and study of several surfactant trans-stilbene derivatives are described.Both compounds containing the trans-stilbene at the hydrophobic terminal of a surfactant chain and those containing an intrachain stilbene chromophore have been studied
