912328-69-9

Basic information

• Product Name: 9-(methoxymethoxy)phenanthrene
• Synonyms: 9-(methoxymethoxy)phenanthrene
• CAS NO: 912328-69-9
• Molecular Weight: 238.286
• Mol File: 912328-69-9.mol

Chemical Properties

• CAS DataBase Reference: 9-(methoxymethoxy)phenanthrene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(methoxymethoxy)phenanthrene(912328-69-9)
• EPA Substance Registry System: 9-(methoxymethoxy)phenanthrene(912328-69-9)

Safety Data

• Hazardous Substances Data: 912328-69-9(Hazardous Substances Data)

Upstream product

• 68572-87-2 9-phenanthrenylboronic acid 

Downstream Products

• 53137-51-2 6,7-dihydro-5H-dibenzocyclohepten-5-one 
• 4444-43-3 2,3;4,5-Dibenztropon 

Relevant articles and documents

Direct Allylic C(sp3)-H Alkylation with 2-Naphthols via Cooperative Palladium and Copper Catalysis: Construction of Cyclohexadienones with Quaternary Carbon Centers

Oxidative allylic C-H alkylation with 2-naphthols was accomplished with excellent chemoselectivities and broad substrate scope through Pd(PPh3)4/Cu(MeCN)4PF6 cooperative catalysis under mild base-free conditions. Special tolerance was observed with peptides, allowing late-stage modifications of peptides. The transformation provides a general protocol to obtain functionalized cyclohexadienones with quaternary carbon centers under two alternative sets of conditions and serves as a complementary catalysis system for the dearomatization of 2-naphthols.