912443-77-7Relevant academic research and scientific papers
Ti(III)-promoted cyclizations. Application to the synthesis of (E)-endo-bergamoten-12-oic acids. Moth oviposition stimulants isolated from Lycopersicon hirsutum
Bermejo, Francisco A.,Fernández Mateos, Alfonso,Marcos Escribano, Andrés,Martín Lago, Rodrigo,Mateos Burón, Lydia,Rodríguez López, María,Rubio González, Rosa
, p. 8933 - 8942 (2006)
The Ti(III)-promoted radical cyclization of epoxyenone 8 is described as the key step to access the diol 10 as a convenient starting material of the target molecules. The synthesis of β-(E)-endo-bergamoten-12-oic acid 2a from (+)-8,9-epoxycarvone 8 was su
