912480-81-0Relevant articles and documents
Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
Schmidtmann, Eric S.,Oestreich, Martin
, p. 3643 - 3645 (2006)
Isotopic desymmetrisation, as well as (stereo)chemical correlation, has illuminated significant aspects of the σ-π-σ mechanism of copper-catalysed allylic substitution reactions: an enantiospecific and regioselective access to α-chiral silanes is presente