91258-36-5Relevant academic research and scientific papers
RING OPENING OF BENZOTHIAZOLES WITH ALLYLIC GRIGNARD REAGENTS
Babudri, F.,Bartoli, G.,Ciminale, F.,Florio, S.,Ingrosso, G.
, p. 2047 - 2050 (2007/10/02)
A novel ring opening reaction of the benzothiazole system with allylic Grignard reagents is reported.A possible mechanism is presented.
REACTION OF 2-HETEROSUBSTITUTED BENZOTHIAZOLES WITH ALLYLIC GRIGNARD REAGENTS
Florio, Saverio,Epifani, Erbana,Ingrosso, Giovanni
, p. 4527 - 4534 (2007/10/02)
The title benzothiazoles 1 react with allylic Grignard reagents affording 2-allylbenzothiazoles 5, 2,2-diallylbenzothiazolines 6 and N-triallylmethyl-o-aminobenzenethiols as disulphides 7 depending upon the experimental conditions.The reaction is considerably influenced by the solvent used and the nature of the allylic Grignard.A possible mechanism for the formation of compounds 5, 6 and 7 is reported.
