912763-40-7

Basic information

• Product Name: 1-methyl-5-(o-tolyl)-1H-pyrrole-2-carboxaldehyde
• Synonyms: 1-methyl-5-(o-tolyl)-1H-pyrrole-2-carboxaldehyde
• CAS NO: 912763-40-7
• Molecular Weight: 199.252
• Mol File: 912763-40-7.mol

Chemical Properties

• CAS DataBase Reference: 1-methyl-5-(o-tolyl)-1H-pyrrole-2-carboxaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-5-(o-tolyl)-1H-pyrrole-2-carboxaldehyde(912763-40-7)
• EPA Substance Registry System: 1-methyl-5-(o-tolyl)-1H-pyrrole-2-carboxaldehyde(912763-40-7)

Safety Data

• Hazardous Substances Data: 912763-40-7(Hazardous Substances Data)

Upstream product

• 1192-58-1 N-methylpyrrole aldehyde 
• 95-46-5 2-methylphenyl bromide 
• 95-49-8 2-methylchlorobenzene 

Relevant articles and documents

Palladium-PEPPSI-NHC Complexes Bearing Imidazolidin-2-Ylidene Ligand: Efficient Precatalysts for the Direct C5-Arylation of N-Methylpyrrole-2-Carboxaldehyde

The Pd-catalyzed direct arylation of pyrroles is an important research field for organic synthesis and catalysis chemistry. However, imidazolidin-2-ylidene based Pd-NHC complexes (NHC=N-heterocyclic carbene) have not yet been employed as catalysts for the

The direct C(sp2)-H functionalization and coupling of aromatic N-heterocycles with (hetero)aryl bromides by [PdX2(imidazolidin-2-ylidene)(Py)] catalysts

In this study, a series of air- and moisture-stable imidazolidin-2-ylidene-based new palladium complexes with the general formula [PdX2(NHC)(Py)] were synthesized (NHC = N-heterocyclic carbene, Py = pyridine, X = Cl or I). The structures of the

Palladium-Polypyrrole Nanocomposites Pd@PPy for Direct C-H Functionalization of Pyrroles and Imidazoles with Bromoarenes

Palladium-polypyrrole nanocomposites (Pd@PPy) with unique combination of high palladium dispersion (nanoparticle size 2.4 nm) and high palladium content (35 wt%) are efficient catalysts for the selective arylation of substituted pyrroles and imidazoles with either activated or deactivated aryl bromides. The performances of the recoverable supported palladium catalyst matches the best performances of homogeneous systems based on Pd(OAc)2 at 0.5-0.2 mol%, and largely overwhelm the classical Pd/C catalyst.

Efficient Pd-catalyzed direct arylations of heterocycles with unreactive and hindered aryl chlorides

A highly electron-rich Pd complex can efficiently catalyze the direct arylation of heteroaromatics with unreactive and sterically congested aryl chlorides.