91301-41-6Relevant academic research and scientific papers
Oxidative α coupling of carbonyl compounds via the condensation of acylated triazolinedione ylides with enolates: A facile synthesis of polyacylated olefins
Wilson, R. Marshall,Hengge, Alvan C.,Ataei, Ali,Ho, Douglas M.
, p. 7240 - 7249 (2007/10/02)
α-Urazolyl ketones are readily oxidized to acylated N-phenyltriazolinedione ylides with tert-butyl hypochlorite. These ylides, usually as generated in situ, undergo condensations with enolate species to form acylated olefins in synthetically useful yields
The Reaction of Cyclic 1,3-Diketones with Alkylcyclopropenium Ions to Yield 2-Alkyltihio-substituted 2H-Pyrans
Yoshida, Hiroshi,Nakajima, Mikito,Ogata, Tsuyoshi,Matsumoto, Kiyoshi
, p. 734 - 738 (2007/10/02)
This study treats the reactions of methylthio-, ethylthio-, or benzylthiodiphenylcyclopropenium ion(1) with 5-, 6-, and 7-membered cyclic 1,3-diketones, giving either 2-alkylthio-2H-pyrans or dienone derivatives.Treatment of 1 with 1,3-cyclopentanedione,
