913076-43-4

Upstream product

• 96-32-2 bromoacetic acid methyl ester 

Downstream Products

• 913076-65-0 (-)-(1R,2S,6R,7R,8R)-5-(3-bromo-2-oxopropyl)-8-tert-butyl(diphenyl)silanyloxy-3-oxa-5-azatricyclo[5.2.1.0^2,6]decan-4-one 
• 913076-52-5 (-)-(1R,2S,6R,7R,8R)-8-tert-butyl(diphenyl)silanyloxy-5-(3-diazo-2-oxopropyl)-3-oxa-5-azatricyclo[5.2.1.0^2,6]decan-4-one 
• 913076-47-8 (-)-(1R,2S,6R,7R,8R)-2-{8-tert-butyl(diphenyl)silanyloxy-4-oxo-3-oxa-5-azatricyclo[5.2.1.0^2,6]dec-5-yl}acetyl chloride 
• 913076-45-6 (-)-(1R,2S,6R,7R,8R)-2-{8-tert-butyl(diphenyl)silanyloxy-4-oxo-3-oxa-5-azatricyclo[5.2.1.0^2,6]dec-5-yl}acetic acid 

Relevant academic research and scientific papers

Diastereoselective [4+3] cycloadditions of enantiopure nitrogen-stabilized oxyallyl cations

Diastereoselective trapping of chiral enantiopure oxyallyl cations by common dienes is reported. Excellent diastereoselectivities were obtained and depending on which auxiliary was used cycloadditions proceeded through a chelated or non-chelated pathway.