91309-68-1Relevant articles and documents
INVESTIGATIONS ON REACTIONS OF CHLORINE DIOXIDE AND SODIUM CHLORITE WITH ORGANIC COMPOUNDS. PART XXXV. REACTIONS OF CHLORINE DIOXIDE WITH RING-SUBSTITUTED STYRENES
Kwiecien, Halina,Jalowiczor, Jozef
, p. 811 - 824 (2007/10/02)
Reactions of chlorine dioxide with ring substituted styrenes (1a-n) in carbon tetrachloride at 52-54 deg C were studied.The reaction products were isolated and characterised.It has been found that methyl-, chloro-, nitrostyrenes and 4-methoxystyrene are attacked by chlorine dioxide exclusively on the vinyl group, to yield the corresponding α-chloroacetophenones (2), diastereoisomers of β-chlorostyrene (6,7), oxidation products (8,9) and some polymers.Oxidation of its phenolic hydroxyl groups and vinyl polymerization took place in hydroxystyrenes.
Photolysis of 3-Chlorodiazirine in the Presence of Alkenes: Orientational Factors in the Intermolecular Interception of Chlorocarbene by Alkenes
Tomioka, Hideo,Hayashi, Norihiro,Izawa, Yasuji,Liu, Michael T. H.
, p. 476 - 478 (2007/10/02)
The stereochemistry of the 1,2-H shift of photolytically generated benzylchlorocarbene is significantly affected by aryl substituents and by the addition of an alkene.