913183-40-1Relevant academic research and scientific papers
Synthesis of the C1-C16 fragment of ionomycin using a neutral (η3-allyl)iron complex
Cooksey, John P.,Kocienski, Philip J.,Li, Ying-Fa,Schunk, Stefan,Snaddon, Thomas N.
, p. 3325 - 3336 (2008/09/16)
Key steps in the synthesis of the C1-C16 polyketide fragment of ionomycin were the nucleophilic addition of an organocuprate to a neutral (η3-allyl)iron complex and the construction of a β-diketone moiety by the Rh-catalysed rearrangement of an
A synthesis of the C1-C9 fragment of ionomycin using cationic η3-allylicmolybdenum and -iron complexes
Cooksey, John,Kocienski, Philip,Li, Ying-Fa
, p. 1653 - 1668 (2007/10/03)
A key step in the synthesis of the C1-C9 fragment of the ionophore antibiotic ionomycin involves the addition of an alkylcopper(I) reagent to an ester-functionalised cationic η3-allylicmolybdenum and an alkylzinc cuprate to the corresponding η
