91319-56-1Relevant articles and documents
Tandem catalysis by lipase in a vinyl acetate-mediated cross-aldol reaction
Kumar, Manjeet,Shah, Bhahwal A.,Taneja, Subhash C.
, p. 1207 - 1212 (2011/06/25)
The lipase Novozym435 (0.6% w/w) was used in tandem with organocatalysts in a first vinyl/isopropenyl acetate-mediated aldol reaction. The reaction was facilitated through the lipase-catalyzed in situ generation of acetaldehyde/acetone. The important features of the present methodology include the mild and facile reaction conditions, regenerability of the lipase, comparatively high yields and minimal side product formation.
Investigations into the use of a polyfluorooctanol as an auxiliary component for an aldol reaction
Eames, Jason,Khanom, Hasina
, p. 266 - 277 (2007/10/03)
Results are reported on the efficiency of polyfluorooctanol as a perfluorous auxiliary component in the aldol reaction between the enolate derived from polyfluorooctyl acetate and 2-fluorobenzaldehyde. Reduction of the corresponding polyfluoro β-hydroxy ester with Super Hydride gave the required 1,3-diol in good yield.