913261-22-0Relevant academic research and scientific papers
2-VINYL INDOLES, PYRIDO AND AZEPINO INDOLE DERIVATIVES, 2-ALKYNYL INDOLES, 2-ALKYNYL BENZO[b]FURANS, THEIR PRECURSORS AND NOVEL PROCESSES FOR THE PREPARATION THEREOF
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Page/Page column 73; 115, (2008/06/13)
The present invention relates to the preparation of 2-vinyl indoles from ortho-gem-dibromovinylaniline compounds and alkene reagents using a palladium pre-catalyst, a base, and, in some instances, a ligand or additive. The present invention also relates t
Synthesis of 2-vinylic indoles and derivatives via a Pd-catalyzed tandem coupling reaction
Fayol, Aude,Fang, Yuan-Qing,Lautens, Mark
, p. 4203 - 4206 (2007/10/03)
(Chemical Equation Presented) A novel one-step synthesis of valuable 2-vinylic indoles and their tricycle derivatives is described. This reaction, which utilizes a gemdibromovinyl unit as a readily available starting material, occurs via an efficient Pd-c
