913548-99-9

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 172681-47-9 3-iodo-2-methylphenylamine 
• 74-88-4 methyl iodide 

Downstream Products

• 1083171-97-4 N-(11-chloro-1,9-dimethyl-5,6-dihydroindazolo[3,2-a]isoquinolin-2-yl)-4,N-dimethylbenzenesulfonamide 
• 1083172-04-6 4,N-dimethyl-N-(10-methyl-5,6-dihydro-[1,2,4]triazolo[5,1-a]isoquinolin-9-yl)-benzenesulfonamide 
• 1083172-09-1 4,N-dimethyl-N-(10-methyl-5,6-dihydro-[1,2,3]triazolo[5,1-a]isoquinolin-9-yl)-benzenesulfonamide 

Relevant academic research and scientific papers

Palladium-Catalyzed Norbornene-Mediated Tandem Amination/Cyanation Reaction: A Method for the Synthesis of ortho-Aminated Benzonitriles

A palladium-catalyzed, norbornene-mediated tandem amination/cyanation reaction via Catellani-type C-H functionalization was developed using N-benzoyloxyamines as the amination reagent and Zn(CN)2 as the terminating agent. This transformation, in which one C-N bond and one C-C bond are formed, provides an efficient approach for the synthesis of ortho-aminated benzonitriles in one pot from easily accessible starting materials.

Synthesis of polycyclic heterocycles via a one-pot ortho alkylation/direct heteroarylation sequence

(Chemical Equation Presented) Polycyclic thiophenes and furans were synthesized using a one-pot ortho alkylation/direct heteroarylation reaction sequence. Under the optimized reaction conditions, aryl iodides were coupled with 3-(bromoalkyl)thiophenes or