91359-31-8Relevant articles and documents
SOME NEW ASPECTS OF CONJUGATE ADDITION OF GRIGNARD AND ALKYLLITHIUM REAGENTS TO VINYLSILANES
Tamao, Kohei,Kanatani, Ryuichiro,Kumada, Makoto
, p. 1905 - 1908 (1984)
A structure and reactivity relationship has been determined on the reaction of isopropyl and n-butyl Grignard reagents and n-butyllithium with vinyl-(alkoxy)silanes and (amino)silanes.The addition to the vinyl group has been analyzed in terms of the nucleophile HOMO-vinyl group LUMO interaction.