913602-80-9Relevant academic research and scientific papers
Two approaches to diverting the course of a free-radical cyclization: Application of cyclopropylcarbinyl radical fragmentations and allenes as radical acceptors
Yang, Dexi,Cwynar, Valerie,Donahue, Matthew G.,Hart, David J.,Mbogo, Grace
supporting information; experimental part, p. 8726 - 8732 (2010/03/02)
(Chemical Equation Presented) Free radical cyclization of 4 and 7 gave the expected cyclization-reduction products (5 and 8) along with considerable amounts of products derived from a cyclization-atom transfer-secondary cyclization process (6 and 9). Two
Quassinoid support studies: Fused carbocycle synthesis from benzoic acid derivatives via 5-hexynyl and 6-heptynyl radical cyclizations
Cwynar, Valerie,Donahue, Matthew G.,Hart, David J.,Yang, Dexi
, p. 4577 - 4580 (2007/10/03)
Eight bromoalkynes were prepared from substituted benzoic acids and treated with n-Bu3SnH to provide trans-fused perhydroindans or cis-and trans-fused perhydronaphthalenes. Atom-transfer reactions that accompany the free radical reactions resul
