913618-67-4Relevant academic research and scientific papers
Alternatives to pyridinediimine ligands: Syntheses and structures of metal complexes supported by donor-modified α-diimine ligands
Schmiege, Benjamin M.,Carney, Michael J.,Small, Brooke L.,Gerlach, Deidra L.,Halfen, Jason A.
, p. 2547 - 2562 (2007)
This report describes the synthesis and characterization of metal halide complexes (M = Mn, Fe, Co) supported by a new family of pendant donor-modified α-diimine ligands. The donor (N, O, P, S) substituent is linked to the α-diimine by a short hydrocarbon
Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
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Page/Page column 48, (2010/11/25)
Methods for making α-diimine metal complexes are described. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an α-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.
