91368-88-6

Basic information

• Product Name: ethyl 3-(t-butoxy)-2-(ethoxycarbonyl)propionate
• Synonyms: ethyl 3-(t-butoxy)-2-(ethoxycarbonyl)propionate
• CAS NO: 91368-88-6
• Molecular Weight: 232.277
• Mol File: 91368-88-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 3-(t-butoxy)-2-(ethoxycarbonyl)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(t-butoxy)-2-(ethoxycarbonyl)propionate(91368-88-6)
• EPA Substance Registry System: ethyl 3-(t-butoxy)-2-(ethoxycarbonyl)propionate(91368-88-6)

Safety Data

• Hazardous Substances Data: 91368-88-6(Hazardous Substances Data)

Upstream product

• 89317-62-4 4-O,O-t-butyl 1-ethyl 2-(ethoxycarbonyl)monoperoxybutanedioate 

Relevant articles and documents

277. Structure and Chemistry of Malonylmethyl- and Succinyl-Radicals. The Search for Homolytic 1,2-Rearrangements

Malonylmethyl radical I and its thioester analogue II were generated by standard photolytic and thermolytic methods from perester and bromo precursors.The structures of I and II were examined by ESR spectroscopy and found to exist in preferred conformations.However, no indication for their rearrangement by 1,2-shift of either an ethoxycarboxyl or (ethylthio)carbonyl group to the corresponding succinyl radicals III and IV, respectively, was found at temperatures below -40 deg C.At higher temperatures of up to 140 deg C, the search for malonylmethyl -> succinyl rearrangement was examined by thorough-product analysis of the perester decomposition.There is evidence for the rearrangement of the radical I to III by photolysis and of the radical II to IV by thermolysis at 130 deg C in chlorobenzene to only a small extent.