913814-44-5Relevant articles and documents
Total synthesis of (+)-aculeatin D and (+)-6-epi-aculeatin D
Yadav,Raghavendra Rao,Ravindar,Subba Reddy
scheme or table, p. 51 - 54 (2010/07/10)
The stereoselective total synthesis of spiroketal natural product (+)-aculeatin D and unnatural (+)-6-epi-aculeatin D has been accomplished. Sharpless kinetic resolution of secondary allylic alcohol and phenyliodine(III) bis(trifluoroacetate) (PIFA)-mediated oxidative spirocyclization were used as key steps in this synthesis. Georg Thieme Verlag Stuttgart.