914093-07-5Relevant academic research and scientific papers
Total synthesis and absolute stereochemistry of polygalolides A and B
Nakamura, Seiichi,Sugano, Yukihito,Kikuchi, Fumiaki,Hashimoto, Shunichi
, p. 6532 - 6535 (2006)
(Chemical Equation Presented) Carbonyl ylides to the fore: the first total synthesis of polygalolides A (1) and B (2) has been achieved by exploiting a tandem carbonyl ylide formation/1,3-dipolar cycloaddition to construct the unprecedented 5,10-dioxatric
Total syntheses of (+)-polygalolide A and (+)-polygalolide B: Elucidation of the absolute stereochemistry and biogenetic implications
Sugano, Yukihito,Kikuchi, Fumiaki,Toita, Akinori,Nakamura, Seiichi,Hashimoto, Shunichi
supporting information; experimental part, p. 9682 - 9690 (2012/09/07)
The total syntheses of (+)-polygalolide A and (+)-polygalolide B have been completed by using a carbonyl ylide cycloaddition strategy. Three of the four stereocenters, including two consecutive tetrasubstituted carbon atoms at C2 and C8, were incorporated
