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CAS

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91410-04-7

[IrHCl(P(C6H5)3)2(C6H4(P(C6H5)2)NCOC6H5)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 91410-04-7 Structure

  • Basic information

    1. Product Name: [IrHCl(P(C6H5)3)2(C6H4(P(C6H5)2)NCOC6H5)]
    2. Synonyms:
    3. CAS NO:91410-04-7
    4. Molecular Formula:
    5. Molecular Weight: 1133.67
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 91410-04-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [IrHCl(P(C6H5)3)2(C6H4(P(C6H5)2)NCOC6H5)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [IrHCl(P(C6H5)3)2(C6H4(P(C6H5)2)NCOC6H5)](91410-04-7)
    11. EPA Substance Registry System: [IrHCl(P(C6H5)3)2(C6H4(P(C6H5)2)NCOC6H5)](91410-04-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 91410-04-7(Hazardous Substances Data)

91410-04-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 91410-04-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,1,4,1 and 0 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 91410-04:
(7*9)+(6*1)+(5*4)+(4*1)+(3*0)+(2*0)+(1*4)=97
97 % 10 = 7
So 91410-04-7 is a valid CAS Registry Number.

91410-04-7Downstream Products

91410-04-7Relevant articles and documents

Synthesis of new hybrid phosphine amide complexes of rhodium(I) and iridium(I). Intramolecular chelate-assisted oxidative addition of an N-H bond to iridium(I)

Hedden, David,Roundhill, D. Max

, p. 9 - 15 (2008/10/08)

The hybrid phosphine amide ligands o-Ph2PC6H4NHC(O)Ph (PNH(CPhO)) and o-Ph2PC6H4C(O)NHPh (P(CO)NHPh)) react with [MCl(1,5-COD)]2 to give the monomeric complexes MCl(1,5-COD)PNH(CPhO)) and MCl(1,5-COD)(P(CO)NHPh) (M = Rh, Ir). The complexes are 4-coordinate with a P-bonded monodentate phosphine amide ligand. P,N-Chelate complexes [M(1,5-COD)(PN(CPh(OH)))]ClO4 and [M(1,5-COD)(P(COH)NPh)]ClO4 (M = Rh, Ir) are formed by the addition of 1 equiv of the ligand to [M(1,5-COD)(THF)2]ClO4. The complexes are proposed to have the hybrid ligand coordinated through a nitrogen in the iminoyl form. Solutions of the complexes in acetonitrile solvent undergo intramolecular exchange. For [Rh(1,5-COD)-(PN(CPh(OH)))]+ this pathway involves replacement of the iminoyl by MeCN, but for [Rh(1,5-COD)(P(COH)NPh)]+ the process involves addition of MeCN into the fifth coordination position. In the case where iminoyl substitution occurs, the dangling ligand arm has the amide structure. The complexes RhCl(1,5-COD)(PNH(CPhO)), RhCl(1,5-COD)(P(CO)NHPh), and IrCl(1,5-COD)(P(CO)NHPh) react with base to give respectively Rh(1,5-COD)(PN(CPhO)), Rh(1,5-COD)(P(CO)NPh), and Ir(1,5-COD)(P(CO)NPh).

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