914365-68-7

Basic information

• Product Name: 3-Furancarboxaldehyde, tetrahydro-3-phenyl-
• CAS NO: 914365-68-7
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 914365-68-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Furancarboxaldehyde, tetrahydro-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Furancarboxaldehyde, tetrahydro-3-phenyl-(914365-68-7)
• EPA Substance Registry System: 3-Furancarboxaldehyde, tetrahydro-3-phenyl-(914365-68-7)

Safety Data

• Hazardous Substances Data: 914365-68-7(Hazardous Substances Data)

Upstream product

• 81462-07-9 4-phenyltetrahydro-2H-pyran-4-ol 
• 3174-81-0 4-phenyl-5,6-dihydro-2H-pyran 
• 29943-42-8 Tetrahydro-4H-pyran-4-one 

Downstream Products

• 936630-09-0 3,4-diphenyl-3,6-dihydro-2H-pyran 
• 936630-13-6 3-(4-methoxyphenyl)-4-phenyl-3,6-dihydro-2H-pyran 
• 936630-11-4 3-(2-methoxyphenyl)-4-phenyl-3,6-dihydro-2H-pyran 
• 936630-12-5 3-(3-methoxyphenyl)-4-phenyl-3,6-dihydro-2H-pyran 
• 936630-10-3 3-(2-methylphenyl)-4-phenyl-3,6-dihydro-2H-pyran 

Relevant articles and documents

Synthesis of cis-3,4-diarylpiperidines and cis-3,4-diaryltetrahydropyrans

Substituted cis-3,4-diarylpiperidines and cis-3,4-diaryltetrahydropyrans are synthesized in modest overall yields starting from 4-aryl-1,2,5,6-tetrahydropyridines and 4-aryl-1,2,5,6-tetrahydropyrans via the following sequence: (1) pinacol-type ring contraction having the?combination of m-chloroperoxybenzoic acid and boron trifluoride etherate, (2) Grignard addition with arylmagnesium bromide reagents and followed by boron trifluoride etherate-mediated intramolecular ring-expanded rearrangement, and (3) hydrogenation with hydrogen on 10% palladium-activated carbon. A facile synthesis of 3,4-diarylpyridines was also described by base-induced aromatization.