914366-90-8Relevant academic research and scientific papers
De novo synthesis of 2-substituted syn-1,3-diols via an iterative asymmetric hydration strategy
Ahmed, Md. Moinuddin,Mortensen, Matthew S.,O'Doherty, George A.
, p. 7741 - 7746 (2007/10/03)
(Chemical Equation Presented) The enantioselective syntheses of several protected 4-substituted syn-3,5-dihydroxy carboxylic esters have been achieved from the corresponding achiral (E,E)- or (E,Z)-1,3-dienoates. The route relies upon an enantio- and regi
Palladium-Catalyzed Selective Hydrogenolysis of Alkenyloxiranes with Formic Acid. Stereoselectivity and Synthetic Utility
Oshima, Masato,Yamazaki, Hiroyuki,Shimizu, Isao,Nisar, Mohammad,Tsuji, Jiro
, p. 6280 - 6287 (2007/10/02)
Selective hydrogenolysis of alkenyloxiranes to give homoallylic alcohols was carried out using formic acid in the presence of palladium-phosphine catalyst.The selectivity of the reaction depends on a nature and an amount of phosphine ligands.The reaction
