914398-75-7Relevant academic research and scientific papers
Polyether macrocycles from intramolecular cyclopropanation and ylide formation. Effect of catalyst and coordination
Weathers Jr., Thomas M.,Wang, Yuanhua,Doyle, Michael P.
, p. 8183 - 8189 (2007/10/03)
The use of catalytic metal carbene methodology with diazoacetates for the construction in high yield of polyether macrocycles having ring sizes greater than 25 has been achieved by preventing access to γ-C-H positions for intramolecular insertion. Cyclopr
