914451-11-9

Basic information

• Product Name: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose
• Synonyms: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose
• CAS NO: 914451-11-9
• Molecular Weight: 458.467
• Mol File: 914451-11-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose(914451-11-9)
• EPA Substance Registry System: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose(914451-11-9)

Safety Data

• Hazardous Substances Data: 914451-11-9(Hazardous Substances Data)

Upstream product

• 914451-05-1 methyl 6-bromo-6-deoxy-2,3,4-tri-O-benzoyl-D-galactopyranoside 
• 774-48-1 (diethoxymethyl)benzene 
• 97-30-3 methyl D-galactopyranoside 
• 914455-48-4 6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 914451-13-1 C₃₀H₂₇NO₉ 
• 914451-12-0 C₂₇H₂₅NO₇ 

Relevant articles and documents

Single diastereomers of polyhydroxylated 9-Oxa-1-azabicyclo[4.2.1]nonanes from intramolecular 1,3-dipolar cycloaddition of ω-unsaturated nitrones

8-Benzyloxymethyl-3,4,5-tribenzoyloxy-9-oxa-1-azabicyclo[4.2.1]nonane has been prepared as the single diastereoisomer 8 from an intramolecular 1,3-dipolar cycloaddition involving 2-(benzyloxy)acetaldehyde and ω-unsaturated hydroxylamine 7 derived from methyl α-D-glucopyranoside. The analogous 8-methoxycarbonyl 9-oxa-1-azabicyclo[4.2.1]nonane was afforded in a similar manner, from methyl D-galactopyranoside and methyl glyoxylate, as a 3:1 mixture of diastereoisomers 15 and 16. When conducted in achiral ionic liquid 17 this ratio increased to 8:1, and in chiral ionic liquid 18, compound 15 was formed exclusively.