91463-90-0Relevant academic research and scientific papers
Extremely Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes
Kaib, Philip S. J.,Schreyer, Lucas,Lee, Sunggi,Properzi, Roberta,List, Benjamin
, p. 13200 - 13203 (2016)
The enantioselective allylation of aldehydes to form homoallylic alcohols is one of the most frequently used carbon–carbon bond-forming reaction in chemical synthesis and, for several decades, has been a testing ground for new asymmetric methodology. Howe
Cp2TiCl2-Catalyzed Photoredox Allylation of Aldehydes with Visible Light
Bergamini, Giacomo,Calogero, Francesco,Cozzi, Pier Giorgio,Fermi, Andrea,Gualandi, Andrea,Guazzi, Simone,Mazzarini, Martino
, p. 3857 - 3863 (2020/03/26)
A Barbier-type Cp2TiCl2-mediated (10 mol %) photoredox allylation of aldehydes under irradiation with visible light (blue light-emitting diodes (LEDs), 450 nm) and in the presence of an organic dye (3DPAFIPN, 5 mol %) with allylbromides is described.
