914651-29-9

Basic information

• Product Name: (3R,4R)-4-isopropyl-3-methyl-3-[((S)-1-methylcyclohex-2-en-1-yl)ethyl]-2-methylenecyclopentanone
• Synonyms: (3R,4R)-4-isopropyl-3-methyl-3-[((S)-1-methylcyclohex-2-en-1-yl)ethyl]-2-methylenecyclopentanone
• CAS NO: 914651-29-9
• Molecular Weight: 274.447
• Mol File: 914651-29-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4R)-4-isopropyl-3-methyl-3-[((S)-1-methylcyclohex-2-en-1-yl)ethyl]-2-methylenecyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R)-4-isopropyl-3-methyl-3-[((S)-1-methylcyclohex-2-en-1-yl)ethyl]-2-methylenecyclopentanone(914651-29-9)
• EPA Substance Registry System: (3R,4R)-4-isopropyl-3-methyl-3-[((S)-1-methylcyclohex-2-en-1-yl)ethyl]-2-methylenecyclopentanone(914651-29-9)

Safety Data

• Hazardous Substances Data: 914651-29-9(Hazardous Substances Data)

Upstream product

• 1026014-56-1 C₂₁HH₃₇OSi 
• 33797-51-2 eschenmoser's salt 
• 62247-44-3 (S)-3-methyl-2-cyclohexenyl acetate 
• 5870-62-2 3-hydroxy-2-cyclopenten-1-one 
• 914651-26-6 3-[(1S,2R,5S)-2-isopropyl-5-methylcyclohexyloxy]cyclopent-2-enone 
• 914651-24-4 (S)-3-(2-iodoethyl)-3-methylcyclohexene 
• 914651-25-5 2-((S)-1-methyl-cyclohex-2-enyl)ethanol 
• 914651-23-3 (R)-4-isopropyl-3-methylcyclopent-2-enone 
• 914651-27-7 (5R)-isopropyl-3-[(1S,2R,5S)-2-isopropyl-5-methylcyclohexyloxy]cyclopent-2-enone 

Downstream Products

• 914651-31-3 (S)-2-{2-[(1R,3R,5R)-3-(tert-butyldimethylsiloxy)-5-isopropyl-1-methyl-2-methylencyclopentyl]ethyl}-2-methylcyclohexanone 

Relevant articles and documents

Enantioselective total synthesis of guanacastepene N using an uncommon 7-endo heck cyclization as a pivotal step

A convergent, enantioselective total synthesis of (+)-guanacastepene N was developed that features a 7-endo Heck cyclization as the key step. In the course of this synthesis, short syntheses of the enantiomerically pure cyclopentenone and cyclohexene buil