Cas 914654-13-0,(tungsten(II))(trimethylphosphane)3(germanium(II)[C6H3-(2,6-C6H2-2,4,6-iPr3)2])(chloride)(hydride)(PMe2CH2)

914654-13-0

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Basic information

Product Name: (tungsten(II))(trimethylphosphane)3(germanium(II)[C₆H₃-(2,6-C₆H₂-2,4,6-iPr₃)2])(chloride)(hydride)(PMe₂CH₂)
Synonyms:
CAS NO:914654-13-0
Molecular Formula:
Molecular Weight: 1077.99
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (tungsten(II))(trimethylphosphane)3(germanium(II)[C₆H₃-(2,6-C₆H₂-2,4,6-iPr₃)2])(chloride)(hydride)(PMe₂CH₂)(CAS DataBase Reference)
NIST Chemistry Reference: (tungsten(II))(trimethylphosphane)3(germanium(II)[C₆H₃-(2,6-C₆H₂-2,4,6-iPr₃)2])(chloride)(hydride)(PMe₂CH₂)(914654-13-0)
EPA Substance Registry System: (tungsten(II))(trimethylphosphane)3(germanium(II)[C₆H₃-(2,6-C₆H₂-2,4,6-iPr₃)2])(chloride)(hydride)(PMe₂CH₂)(914654-13-0)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 914654-13-0(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 914654-13-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,1,4,6,5 and 4 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 914654-13:
(8*9)+(7*1)+(6*4)+(5*6)+(4*5)+(3*4)+(2*1)+(1*3)=170
170 % 10 = 0
So 914654-13-0 is a valid CAS Registry Number.

914654-13-0Upstream product

218900-77-7 Ge(Cl)C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2

914654-13-0Downstream Products

914654-13-0Relevant academic research and scientific papers

Activation of aryl germanium(II) chlorides by [Mo(PMe3) 6] and [W(η2-CH2PMe2)H(PMe 3)4]: A new route to metal-germanium triple bonds

Filippou, Alexander C.,Weidemann, Nils,Philippopoulos, Athanassios I.,Schnakenburg, Gregor

, p. 5987 - 5991 (2006)

(Chemical Equation Presented) A new activation mode of aryl germanium(II) chlorides at electron-rich metal centers leads to compounds featuring metal-germanium triple bonds. Reaction of 1 with RGeCl affords the hydridogermylidene complex 2, which rearranges thermally to give the germylidyne complex 3 (see scheme; Trip = C6H2-2,4,6-iPr 3). In contrast, the reaction of [Mo(PMe3)6] with RGeCl yields directly the germylidyne complex trans-[CI(PMe 3)4Mo≡GeR].

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