914769-32-7

Upstream product

• 89-78-1 1R,2RS,4S-(-)-menthol 

Downstream Products

• 1441778-34-2 ((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)diphenylphosphine sulfide 
• 1441778-39-7 ((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)diphenylphosphine sulfide 
• 1441778-25-1 ((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)(methyl)sulfane 
• 116560-69-1 ((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)(methyl)sulfane 

Relevant academic research and scientific papers

Iron-Catalyzed Oxyalkylation of Terminal Alkynes with Alkyl Iodides

A general oxyalkylation of terminal alkynes enabled by iron catalysis has been developed. Primary and secondary alkyl iodides acted as the alkylating reagents and afforded a range of α-alkylated ketones under mild reaction conditions. Acetyl tert-butyl peroxide (TBPA) was used as the radical relay precursor, providing the initiated methyl radical to start the radical relay process. Preliminary mechanistic studies were conducted, and late-stage functionalizations of natural product derivatives were performed.