915015-31-5

Basic information

• Product Name: [2-((2-Br-4,6-F₂-C₆H₂)NC(Me))-1,10-phen]FeCl₂
• CAS NO: 915015-31-5
• Molecular Weight: 538.989
• Mol File: 915015-31-5.mol

Chemical Properties

• CAS DataBase Reference: [2-((2-Br-4,6-F₂-C₆H₂)NC(Me))-1,10-phen]FeCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: [2-((2-Br-4,6-F₂-C₆H₂)NC(Me))-1,10-phen]FeCl₂(915015-31-5)
• EPA Substance Registry System: [2-((2-Br-4,6-F₂-C₆H₂)NC(Me))-1,10-phen]FeCl₂(915015-31-5)

Safety Data

• Hazardous Substances Data: 915015-31-5(Hazardous Substances Data)

Upstream product

• 915016-96-5 2-acetyl-1,10-phenanthroline(2-bromo-4,6-difluoroanil) 

Relevant articles and documents

Iron(II) complexes ligated by 2-imino-1,10-phenanthrolines: Preparation and catalytic behavior toward ethylene oligomerization

A series of N,N,N-tridentate iron (II) complexes bearing 2-imino-1,10-phenanthrolines, [2-{(2,6-R1,R3-4-R2-C6H2)N{double bond, long}C(R)}-1,10-phen]FeCl2, was synthesized and characterized by IR spectroscopy and elemental analysis. One of these complexes (18b) was determined by single-crystal X-ray crystallography for its unambiguous structure. These iron(II) complexes were found to exhibit remarkable activities for ethylene oligomerization in the presence of MAO or MMAO cocatalyst affording α-olefins with high selectivity and the composition of oligomers followed the Schluz-Flory distribution. The effects of substituents on imino fragment on the activity were explored in detail; complexes with mono substituent at the ortho-position of the phenyl ring showed high activities with low K values, suggesting that fine tuning of the steric bulk of substituents on the imino fragment directly affects both the activity and the selectivity.