91510-87-1

Basic information

• Product Name: 2-methyl-3-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)propene
• CAS NO: 91510-87-1
• Molecular Weight: 578.748
• Mol File: 91510-87-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-methyl-3-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)propene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-3-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)propene(91510-87-1)
• EPA Substance Registry System: 2-methyl-3-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)propene(91510-87-1)

Safety Data

• Hazardous Substances Data: 91510-87-1(Hazardous Substances Data)

Upstream product

• 67883-62-9 2-methylallyltributyltin 
• 91602-61-8 phenyl 2,3,4,6-tetra-O-benzyl-1-thio-α/β-D-glucopyranoside 
• 18292-38-1 2-methallyltrimethylsilane 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 3879-79-6 (2R,3R,4S,5S,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran 

Relevant articles and documents

8-(Methyltosylaminoethynyl)-1-naphthyl (MTAEN) Glycosides: Potent Donors in Glycosides Synthesis

With 8-(methyltosylaminoethynyl)-1-naphthyl (MTAEN) glycoside as donors, a novel and efficient glycosylation protocol has been established. The MTAEN glycosylation protocol exhibits the merits of shelf-stable donors, mild catalytic promotion conditions, considerably extended substrate scope encompassing both free alcohols, silylated alcohols, nucleobases, primary amides, and C-type nucleophile acceptors, and applicability to various one-pot strategies for highly efficient synthesis of oligosaccharides, such as orthogonal one-pot, single-catalyst one-pot, and acceptor reactivity-controlled one-pot strategies.

HIGHLY STEREOSELECTIVE C-ALLYLATION OF GLYCOPYRANOSIDES WITH ALLYLSILANES CATALYZED BY SILYL TRIFLATE OR IODOSILANE

Methyl α-D-glucopyranoside, methyl α-D-mannopyranoside and, in particular, the corresponding α-D-glycopyranosyl chlorides readily undergo allylation with allylsilanes catalyzed by trimethylsilyl triflate or iodotrimethylsilane in a highly stereoselective mode.