915137-63-2Relevant articles and documents
β-disubstituted allylic chlorides: Substrates for the Cu-catalyzed asymmetric SN2′ reaction
Falciola, Caroline A.,Tissot-Croset, Karine,Alexakis, Alexandre
, p. 5995 - 5998 (2006)
Scope broadened: A previously developed asymmetric Cu-catalyzed allylic substitution can be applied to more substituted allylic patterns. Two classes of β-disubstituted substrates, cinnamyl derivatives and aliphatic endocyclic allylic chlorides, afford excellent regio- and enantioselectivities (see schemes; L* = phosphoramidite ligand). (Chemical Equation Presented).
