915285-99-3Relevant academic research and scientific papers
An easy route toward enantio-enriched polycyclic derivatives via an asymmetric domino conjugate reduction-aldol cyclization catalyzed by a chiral Cu(I) complex
Deschamp, Julia,Hermant, Thomas,Riant, Olivier
experimental part, p. 3457 - 3467 (2012/06/16)
A highly efficient reductive-aldol cyclization mediated by a chiral Cu(I) complex and an organosilane yielded to cyclic or polycyclic derivatives. An excellent control of the selectivities was reached in most cases (dr up to 100:0 and ee up to 95%). After
Inversion of diastereoselectivity depending on substrate concentration in baker's yeast catalyzed reduction of σ-symmetrical 1,3-cyclopentadiones and 1,3-cyclohexadiones
Katoh, Takahiro,Mizumoto, Shinsuke,Fudesaka, Masato,Nakashima, Yuki,Kajimoto, Tetsuya,Node, Manabu
, p. 2176 - 2182 (2007/10/03)
Inversion of diastereoselectivity caused by a change in substrate concentration was first observed in baker's yeast catalyzed reduction of σ-symmetrical 2,2-dialkylated cyclopentan-1,3-diones 1,2 and cyclohexan-1,3-dione 20. The selectivity altered by deg
