91552-65-7

Upstream product

• 10472-64-7 2,5-diisopropylnitrobenzene 
• 100-18-5 1,4-bis(1-methylethyl)benzene 

Downstream Products

• 119435-76-6 4-(2,5-Diisopropyl-phenylazo)-benzoic acid 
• 33685-58-4 2,5-diisopropylcyclohexa-2,5-diene-1,4-dione 
• 35946-91-9 2,5-Diisopropylphenol 
• 1369822-44-5 C₁₄H₂₃N 
• 860532-28-1 2,5-diisopropyl-3-nitro-aniline 
• 88702-22-1 acetic acid-(2,5-diisopropyl-anilide) 
• 94913-59-4 benzoic acid-(2,5-diisopropyl-anilide) 

Relevant academic research and scientific papers

MOLECULES HAVING CERTAIN PESTICIDAL UTILITIES, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES RELATED THERETO

This disclosure relates to compounds having pesticidal utility against pests in phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such compounds and intermediates used in such processes, compositions containing such compounds, and processes of using such compounds against such pests. These compounds/molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses compounds having the following formula (Formula One and/or Formula One-A).

The reaction of nitrile oxide-quinone cycloadducts. III. Reinvestigation of the base-induced isomerization of the 1:1 -C=C-adducts of aromatic nitrile oxides with 2,5-and 2,6-dialkyl-substituted p-benzoquinones

The structure of the product obtained by the base, induced isomerization of the 1,3-dipolar cycloadduct of 2,5-di-t-butyl-p-benzoquinone with 2,6- dichlorobenzonitrile oxide was determined by X-ray analysis. The t-butyl group at the bridgehead position of the 1,3-dipolar cycloadduct migrated to the neighboring carbonyl carbon atom. This base-induced rearrangement took place with a bulky group, i.e., Et, i-Pr, t-Bu, and Bn at the bridgehead position of nitrile oxide-quinone cycloadducts in an alcoholic media. The driving force of this reaction is considered to be due to stabilization by aromatization from isoxazoline derivatives to isoxazole-fused p-quinol derivatives.