91553-19-4Relevant academic research and scientific papers
Chemical Behavior of N-Alkyl-N-methylbenzylammonium N-Alkylide
Okazaki, Seiji,Shirai, Naohiro,Sato, Yoshiro
, p. 334 - 337 (2007/10/02)
N-Alkyl-N-methyl(4-substituted benzyl)ammonium N-alkylides (3), produced by fluoride ion induced desilylation of N-alkyl-N-methyl-N-(4-substituted benzyl)-1-(trimethylsilyl)alkylammonium iodides (2), were mainly converted into N-alkyl-N-methyl-1-(4-substituted benzyl)alkylamines (5, Stevens rearrangement products) and 4-substituted toluenes (8).Both compounds were produced via radical-forming and -destroying pathways from 2-substituted-6--5-methylene-1,3-cylohexadienes (4), which were initially formed from 3 by sigmatropic rearrangement.There is no direct migration pathway from 3 to 5.
