915769-32-3

Upstream product

• 37234-97-2 copper(I) trifluoromethanesulfonate benzene 
• 915769-28-7 [N((C₃F₇)C(2-F,6-(CF₃)C₆H₃)N)2]H 
• 201230-82-2 carbon monoxide 
• 34946-82-2 copper(I) triflate 

Relevant academic research and scientific papers

Poly-halogenated Triazapentadiene Compositions

A new class of fluorinated or polyhalogenated triazapentadienes are disclosed. The synthesized triazapentadienes are thermally stable, soluble in typical solvents and have several metal binding sites for complexation with metal ions. The compounds are prepared as colorless crystalline solids. Synthesis takes advantage of a reaction with triethylamine. Synthesized triazapentadienes (with and without complexed metals) inhibit bacterial growth of both Gram positive and Gram-negative bacteria.

Syntheses of highly fluorinated 1,3,5-triazapentadienyl ligands and their use in the isolation of copper(I)-carbony and copper(I)-ethylene complexes

Fully fluorinated triazapentadienyl ligand [N{(C3F 7)C(C6F5)N}2]- and the related [N{(C3F7)C(2-F,6-(CF3)C 6H3)N}2]- have been synthesized in good yield via a convenient route and used in the isolation of three- and four-coordinate copper(I)-carbon monoxide complexes. They show fairly high νCO values (>2100 cm-1), indicating the presence of electron-poor Cu sites. The copper(I)-ethylene adduct [N{(C3F 7)C(C6F5)N}2]Cu(C2H 4), featuring a three-coordinate Cu site, has also been synthesized using [N{(C3F7)C-(C6F5)N} 2]CuNCCH3 and C2H4.