915776-02-2

Upstream product

• 915775-92-7 N,N-bis(tert-butyldimethylsilyloxy)-1-(phenylthio)ethenamine 
• 623-48-3 ethyl iodoacetae 
• 915775-87-0 (1-Nitro-ethylsulfanyl)-benzene 
• 69739-34-0 t-butyldimethylsiyl triflate 

Relevant academic research and scientific papers

Radical alkylation of bis(silyloxy)enamine derivatives of organic nitro compounds

(Chemical Equation Presented) Alkylation β to a nitro group by radical chemistry is made possible by initial conversion of the organic nitro compound into a bis(silyloxy)enamine (see scheme; TBSOTf=tert-butyldimethylsilyl trifluoromethanesulfonate). An advantage of the method is the simultaneous conversion of the nitro group into a synthetically useful oxime ether group.