915790-36-2Relevant academic research and scientific papers
Alternative total synthesis of (+)-aspicilin
Musulla, Sridhar,Bharathi Kumari,Madala, Mahesh,Srinivasa Rao,Naresh, Vema Venkata
, p. 1657 - 1662 (2018)
The total synthesis of an 18-membered polyhydroxylated macrolide (+)-Aspicilin was accomplished starting from commercially available enantiopure propylene oxide and D-(+)-gluconolactone by asymmetric synthetic approach. The key reactions involved are Witt
A concise total synthesis of the lichen macrolide (+)-aspicilin
Dubost, Christophe,Marko, Istvan E.,Ryckmans, Thomas
, p. 5137 - 5140 (2007/10/03)
(Figure Presented) The total synthesis of the polyhydroxylated macrolide (+)-aspicilin 5 is described using as a key step a highly diastereoselective allylation of aldehyde 6 with the uniquely functionalized allylstannane 1. (+)-Aspicilin is obtained in 1
