91582-69-3Relevant academic research and scientific papers
Sequential electrophilic P-C bond formation in metal-coordinated chlorophosphines
Jayaraman, Arumugam,Jacob, Tyler V.,Bisskey, Jeff,Sterenberg, Brian T.
, p. 8788 - 8791 (2015)
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P-C bond formation. This methodology can be applied sequential
POTENTIEL SYNTHETIQUE DES AMINOPHOSPHINES SECONDAIRES COMPLEXEES
Marinetti, Angela,Mathey, Francois
, p. 311 - 318 (2007/10/02)
Several synthetic schemes have been devised starting from pentacarbonyltungsten 1.Metalation of the P-H bond of 1 by butyllithium followed by reaction with allyl bromide afforded penta
