Cas 91602-77-6,{(+)-(S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine)}(η4-8,9,10-trinorborna-2,5-diene)-rhodium(I) tetrafluoroborate

91602-77-6

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Basic information

Product Name: {(+)-(S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine)}(η4-8,9,10-trinorborna-2,5-diene)-rhodium(I) tetrafluoroborate
Synonyms:
CAS NO:91602-77-6
Molecular Formula:
Molecular Weight: 832.47
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: {(+)-(S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine)}(η4-8,9,10-trinorborna-2,5-diene)-rhodium(I) tetrafluoroborate(CAS DataBase Reference)
NIST Chemistry Reference: {(+)-(S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine)}(η4-8,9,10-trinorborna-2,5-diene)-rhodium(I) tetrafluoroborate(91602-77-6)
EPA Substance Registry System: {(+)-(S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine)}(η4-8,9,10-trinorborna-2,5-diene)-rhodium(I) tetrafluoroborate(91602-77-6)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 91602-77-6(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 91602-77-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,1,6,0 and 2 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 91602-77:
(7*9)+(6*1)+(5*6)+(4*0)+(3*2)+(2*7)+(1*7)=126
126 % 10 = 6
So 91602-77-6 is a valid CAS Registry Number.

91602-77-6Upstream product

91602-77-6Downstream Products

91602-77-6Relevant academic research and scientific papers

2,2'-Dimethyl-6,6'-bis(diphenylphosphino)biphenyl (BIPHEMP) as a Chiral Ligand for Transition Metal Catalyzed Asymmetric Synthesis of Binaphthyls and for Asymmetric Hydrogenation. A Comparison with BINAP

Frejd, Tornbjoern,Klingstedt, Tomas

, p. 670 - 675 (2007/10/02)

The chiral biphosphine ligand 1 has been prepared via optically active 2,2'-dilithio-6,6'-dimethyldiphenyl and used in the synthesis of optically active binaphthyls through palladium catalyzed c

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