916085-16-0Relevant academic research and scientific papers
Organolithium-mediated conversion of β-alkoxy aziridines into allylic sulfonamides: Effect of the N-sulfonyl group and a formal synthesis of (±)-perhydrohistrionicotoxin
Coote, Susannah C.,Moore, Stephen P.,O'Brien, Peter,Whitwood, Adrian C.,Gilday, John
, p. 7852 - 7855 (2008/12/22)
(Chemical Equation Presented) In 18 out of 20 examples of the organolithium-mediated conversion of β-alkoxy aziridines into substituted allylic sulfonamides, use of a Bus (Bus = t-BuSO2) substituent on the nitrogen gave higher yields compared t
New route to azaspirocycles via the organolithium-mediated conversion of β-alkoxy aziridines into cyclopentenyl amines
Moore, Stephen P.,Coote, Susannah C.,O'Brien, Peter,Gilday, John
, p. 5145 - 5148 (2007/10/03)
(Chemical Equation Presented) A new three-step route to azaspirocycles involving the organolithium-mediated conversion of β-alkoxy aziridines into substituted cyclopentenyl amines, hydroboration, and cyclization has been developed. The methodology is util
